物质的标准摩尔生成焓

物质的标准摩尔生成焓、标准摩尔生成吉布斯函数、

标准摩尔熵和摩尔热容(100kPa)>

(1) 单质和无机物 物质 Ag(s) Ag2CO3(s) Ag2O(s) Al(s) Al(g) Al2O3-αBr2(g) Br2(g) Br2(l) C(g) C(金刚石) C(石墨) CO(g) CO2(g) Ca(s) CaC2(s) CaCO3(方解石) CaCl2(s) CaO(s) Ca(OH)2(s) CaSO4(硬石膏) Cl-(aq) Cl2(g) Cu(s) CuO(s) Cu2O-αF2(g) Fe-αΔfHm(298.15K) kJ·mol0 -506.14 -30.56 0 313.80 -1ΔfGm(298.15K) kJ·mol0 -437.09 -10.82 0 273.2 -2213.16 -3728.53 82.396 3.109 0 672.942 2.866 0 -137.285 -394.38 0 -67.8 -1128.70 -750.2 -604.2 -896.89 -1320.24 -131.168 0 0 -127.1 -146.33 0 0 -673.84 -244.3 -741.0 -1014.1 203.122 0 0 -53.22 -102.80 -95.265 -131.17 -623.37 -1Sm(298.15K) J·K-1molCp,m(298.15K) J·K-1·mol 65.57 24.35 79.0 259.4 35.99 35.6 6.07 8.66 29.142 37.120 26.27 62.34 81.83 72.63 48.53 84.5 97.65 33.9 24.47 44.4 69.8 31.46 25.23 82.13 51.1 104.6 143.42 20.80 28.83 29.20 29.12 29.12 -1 -1669.8 -3434.98 111.884 30.71 0 718.384 1.896 0 -110.525 -393.511 0 -62.8 -1206.87 -795.0 -635.6 -986.5 -1432.68 -167.456 0 0 -155.2 -166.69 0 0 -747.68 -266.52 -822.1 -117.1 217.94 0 0 -36.24 -120.92 -92.311 -167.44 -698.7 Al2(SO4)3(s) FeCO3(s) FeO(s) Fe2O3(s) Fe3O4(s) H(g) H2(g) D2(g) HBr(g) HBr(aq) HCl(g) HCl(aq) H2CO3(aq) 42.712 167.36 121.71 28.315 164.553 0.986 239.3 175.021 245.455 152.3 158.101 2.439 5.694 198.016 213.76 41.63 70.2 92.8 113.8 39.7 76.1 106.7 55.10 222.948 33.32 43.51 100.8 203.5 27.15 92.8 54.0 90.0 146.4 114.724 130.695 144.884 198.60 80.71 186.786 55.10 191.2 -1 25.48 1

Hl(g) H2O(g) H2O(l) H2O(s) H2O2(l) H2S(g) H2SO4(l) H2SO4(aq) HSO4(aq) l2(g) I2(g) N2(g) NH3(g) NO(g) NO2(g) N2O(g) N2O4(g) N2O5(g) O(g) O2(g) O3(g) OH-(aq) S(单斜) S(斜方) (g) S(g) SO2(g) SO3(g) SO4 (aq) 2--25.94 -241.825 -285.838 -291.850 -187.61 -20.146 -811.35 -811.32 -885.75 0 62.242 0 -46.19 89.860 33.85 81.55 9.660 2.51 247.521 0 142.3 -229.940 0.29 0 124.94 222.80 -296.90 -395.18 -907.51 -1.32 -228.577 -237.142 (-234.03） -118.04 -33.040 (-866.4） -752.99 0 19.34 0 -16.603 90.37 51.86 103.62 98.39 110.5 230.095 0 163.45 -157.297 0.096 0 76.08 182.27 -300.37 -370.40 -741.90 206.42 188.823 69.940 (39.4） 102.26 205.75 156.85 126.86 116.7 260.60 191.598 192.61 210.309 240.57 220.10 304.42 342.4 161.063 205.138 237.7 -10.539 32.55 31.9 227.76 167.825 248.64 256.34 17.2 29.12 33.571 75.296 82.29 33.97 137.57 55.97 36.87 29.12 35.65 29.861 37.90 38.70 79.0 108.0 21.93 29.37 38.15 23.64 22.60 32.55 39.79 50.70

(2)有机化合物 物质 ΔfHm(298.15K) ΔfGm(298.15K) Sm(298.15K) Cp,m(298.15K) kJ·mol-1 kJ·mol烃 类 -1 J·K-1mol-1 J·K-1·mol-1 CH4(g), 甲烷 C2H2(g), 乙炔 C2H4(g), 乙烯 C2H6 乙烷 -74.847 226.748 52.283 -84.667 20.414 50.827 209.200 68.157 -32.821 62.783 186.30 200.928 219.56 229.60 267.05 35.715 43.928 43.56 52.650 63.89 C3H6(g), 丙烯 2

C3H6(g), 丙烷 C4H6(g), 1,3-丁二烯 C4H8(g), 1-丁烯 C4H8(g), 顺-2-丁烯 C4H8(g), 反-2-丁烯 C4H8(g), 2-甲基两烯 C4H10(g), 正丁烷 C4H10(g), 异丁烷 C6H6(g), 苯 C6H6(l), 苯 C6H12(g), 环己烷 C6H14(g), 正己烷 C6H14(l), 正己烷 C6H5CH3(g),甲苯 C6H5CH3(l),甲苯 C6H4(CH2）邻二甲苯 -103.847 110.16 -0.13 -6.99 -11.17 -16.90 -126.15 -134.52 82.927 49.028 -123.14 -167.19 -198.82 49.999 11.995 18.995 -24.439 17.238 -25.418 17.949 -24.426 -23.391 150.74 71.60 65.96 63.07 58.17 -17.02 -20.79 129.723 124.597 31.92 -0.09 -4.08 122.388 114.299 122.207 110.495 118.977 107.817 121.266 110.244 270.02 278.85 305.71 300.94 296.59 293.70 310.23 294.75 269.31 172.35 298.51 388.85 295.89 319.86 219.58 352.86 246.48 357.80 252.17 352.53 247.36 73.51 79.54 8565 78.91 87.82 89.12 97.45 96.82 81.67 135.77 106.27 143.09 194.93 103.76 157.11 133.26 187.9 127.57 183.3 126.86 183.7 C6H4（CH3）2(l),邻二甲苯 C6H4（CH3）2(g),间二甲苯 C6H（CH3）2（l), 间二甲苯 C6H4（CH3）2对二甲苯 C6H4（CH3）2(l), 对二甲苯 含 氧 化 合 物 HCOH(g), 甲醛 HCOOH(g), 甲酸 HCOOH(l), 甲酸 CH3OH(g), 甲醇 CH3OH(l), 甲醇 CH2COH(g), 乙醛 CH3COOH(l), 乙酸 CH3COOH(g), 乙酸 C2H5OH(l), 乙醇 -115.90 -362.63 -409.20 -201.17 -238.57 -166.36 -487.0 -436.4 -277.63 -110.0 -335.69 -345.9 -161.83 -166.15 -133.67 -392.4 -381.5 -174.36 220.2 251.1 128.95 237.8 126.8 265.8 159.8 293.4 160.7 35.36 54.4 99.04 49.4 81.6 62.8 123.4 72.4 111.46 3

C2HOH(g), 乙醇 CH3COCH3（l),丙酮 CH3COCH3(g),丙酮 C2H5OC2H5(l),乙醚 CH3COOC2H5(l), 乙酸乙酯 C6H5COOH（s), 苯甲酸 -235.31 -248.283 -216.69 -273.2 -463.2 -384.55 -168.54 -155.33 -152.2 -116.47 -315.3 -245.5 卤 代 烃 CH3Cl(g), 氯甲烷 CH2Cl2(g), 二氯甲烷 CHCl3（l), 氯仿 CHCl3(g), 氯仿 CCl4(l), 四氯化碳 CCl4(g), 甲氯化碳 C6H5Cl(l), 氯苯 -82.0 -88 -131.8 -100 -139.3 -106.7 116.3 -58.6 -59 -71.4 -67 -68.5 -64.0 -198.2 234.29 270.62 202.9 296.48 214.43 309.41 197.5 40.79 51.38 116.3 65.81 131.75 85.51 145.6 282.1 200.0 296.00 253.1 259 170.7 71.1 124.73 75.3 155.2 含 氮 化 合 物 NH（CH3）2(g), 二甲胺 C5H5N(l), 吡啶 C6H5NH2(l), 苯胺 C6H5NO2 (l)，硝基苯 -27.6 78.87 35.31 15.90 59.1 159.9 153.35 146.36 273.2 179.1 191.6 244.3 69.37 199.6 本附录数据主要取自Handbook of Chemistry and Physics, 70 th Ed., 1990; Editor John A.Dean,Lange's Handbook of Chemistry, 1967。

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