SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Lupolen 2426K Ethene, homopolymer, PE Polyethylene 9002-88-4 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture 1.3 Details of the supplier of the safety data sheet Company Telephone Registration number Basell Sales & Marketing 31 (0) 10 275 55 NA Company B.V. 00 Groot Handelsgebouw, Stationsplein 45 3013 AK Rotterdam Netherlands E-mail address : product.safety@lyondellbasell.com Responsible/issuing person 2. Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. Classification according to EU Directives 67/548/EEC or 1999/45/EC, as amended Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements Labeling (REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. 2.3 Other hazards If small particles are generated during further processing, handling or by other means, may form combustible dust concentrations in air. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB). 1 / 13 1.4 Emergency telephone Emergency telephone +32 3 575 1235 : Manufacture of plastic articles by injection moulding, extrusion or other conversion process. Trade name Synonyms Substance name Substance No. : : : : SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 3. Composition/information on ingredients 3.2 Mixtures Ingredients Chemical Name CAS-No. EC-No. Classification (67/548/EEC) Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 Polyethylene 9002-88-4 Not Classified Classification (REGULATION (EC) No 1272/2008) Not Classified Weight % > 99.5 % Contains: Additives and stabilizers 4. First aid measures 4.1 Description of first-aid measures General advice If inhaled : Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid. : Remove person to fresh air. If signs/symptoms continue, get medical attention. In case of excessive inhalation of fumes that may be generated during heating of this material, move the person to fresh air. Obtain medical attention. Keep person warm, if necessary give Cardio-Pulmonary Resuscitation (CPR) : If molten material contacts the skin, immediately flush with large amounts of water to cool the affected tissue and polymer. Do not attempt to peel polymer from skin as this will remove the skin. Obtain immediate emergency medical attention if burn is deep or extensive. : Flush eyes thoroughly with water for several minutes and seek medical attention if discomfort persists. : In case of eye contact with molten polymer: Continuously flush eye(s) with cool running water for at least 15 minutes. Beyond flushing, DO NOT attempt to remove the material adherent to the eye(s). Immediately seek medical attention. : Adverse health effects due to ingestion are not anticipated. 2 / 13 In case of skin contact In case of eye contact If swallowed SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 4.2 Most important symptoms and effects, both acute and delayed Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 : Inhalation of process fumes and vapors may cause soreness in the nose and throat and coughing. Hazards : Dust contact with the eyes can lead to mechanical irritation. Molten polymer may cause thermal burns. 4.3 Indication of any immediate medical attention and special treatment needed Treatment 5. Fire-fighting measures 5.1 Extinguishing media : SMALL FIRE: Use dry chemical, CO2, or water spray. : LARGE FIRES: Use water spray hose nozzles from a safe location. Unsuitable extinguishing : None known. media 5.2 Special hazards arising from the substance or mixture Specific hazards during fire fighting : Keep away from heat and sources of ignition. In case of fire hazardous decomposition products may be produced such as: Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). : Wear approved positive pressure self-contained breathing apparatus and firefighter protective clothing. : Combustible particulate solid, will decompose under fire conditions. Calorific Value: 8000 - 11000 kcal/kg Fight fire from safe distance with hose lines or monitor nozzles. Heat from fire may melt, decompose polymer, and generate flammable vapors. Move containers from fire area if it can be done without risk. Evacuate immediately in the event of opening of storage container pressure relief devices or discoloration of container. Always stay away from tanks engulfed in fire. Do not attempt to get on top of storage containers involved in 3 / 13 Suitable extinguishing media : Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. Symptoms 5.3 Advice for firefighters Special protective equipment for fire-fighters Further information SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 fire. Cool storage containers with large volumes of water even after fire is out. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Equip responders with proper protection. Creates dangerous slipping hazard on any hard smooth surface. Equip emergency responders with proper personal protective equipment (PPE) Avoid generating dust. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Potential combustible dust hazard. Polymer particles create slipping hazard on hard smooth surfaces. 6.2 Environmental precautions : Do not flush into surface water or sanitary sewer system. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : On land, sweep/shovel into suitable disposal containers or vacuum using equipment which avoids ignition risk. On water, material is insoluble; collect and contain as any solid. All recovered material should be packaged, labeled, transported and disposed of or reclaimed in conformance with applicable laws and regulations and in conformance with good engineering practices. Reclaim where possible. Environmental precautions 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Material is in a pellet form. If converted to small particles during further processing, handling, or by other means, may form combustible dust concentrations in air. Avoid dust accumulation in enclosed space. Use dust collection systems designed in accordance with ATEX 95. Avoid generating dust; fine dust suspended in air and in the presence of an ignition source is a potential dust explosion hazard. 4 / 13 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 Fire-fighting class Static discharge (spark), or other ignition sources, in high dust environments may ignite the dust and result in a dust explosion Electrostatic charge may build during conveying or handling. Equipment handling polymer should be conductive and grounded (earthed) and bonded. Metal containers involved in the transfer of this material should be grounded and bonded. All electrical equipment should conform to applicable electric codes and regulatory requirements for areas handling combustible dusts. After handling, always wash hands thoroughly with soap and water. When bringing the material to processing temperatures vapors may develop may condense in the exhaust ventilation. See section 10. : Refer to ATEX 95 and ATEX 137 and related Harmonized European Standards: EN 1127-1 (Explosive atmospheres – Explosion prevention and protection). : Polymer will burn but does not easily ignite. : Store in a dry location. Use good housekeeping practices during storage, transferring and handling. Process enclosures and adequate ventilation should be used to avoid excessive dust accumulation. Store away from excessive heat and away from strong oxidizing agents. Keep container closed to prevent contamination. Take measures to prevent the build up of electrostatic charge. : See Section 1.2. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers 7.3 Specific end use(s) 8. Exposure controls/personal protection 8.1 Control parameters Ingredients with workplace control parameters Occupational Exposure Limits Ingredients CAS-No. Type Limit Value 5 / 13 Basis Additional SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Materials that can be formed when handling this product: Non-specified (inert or nuisance) dust Materials that can be formed when handling this product: Non-specified (inert or nuisance) dust TWA 10 mg/m3 inhalable Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 Revision Date US (ACGIH) 2005 Information TWA 3 mg/m3 respirable US (ACGIH) 2005 Consult local authorities for acceptable exposure limits. 8.2 Exposure controls Engineering measures In accordance with ATEX 137, follow the recommendations in EN 1127-1(Explosive atmospheres – Explosion Prevention and protection). Follow the recommendations in international standard NFPA 654 (as amended and adopted) for equipment used to handle this product. Engineering controls, i.e. enclosed systems, should be used whenever feasible to maintain exposures below acceptable criteria. When such controls are not feasible, or sufficient to achieve full conformance, other engineering controls such as local exhaust ventilation should be used. Equipment and vessels handling combustible dust from this material should be designed to either prevent dust explosions (inerting) or safely vent dust explosions per ATEX 95 and related Harmonized European Standards. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). Personal protective equipment Respiratory protection : Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Use appropriate respiratory protection where atmosphere exceeds recommended limits. Where workers could be exposed to dust concentratons above the exposure limit they must use appropriate certified respirators. : Wear gloves that provide thermal protection where there is a 6 / 13 Hand protection SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 potential for contact with heated material. Eye and face protection : Dust service goggles should be worn to prevent mechanical injury or other irritation to eyes due to airborne particles which may result from handling this product. Skin and body protection : Wear suitable protective clothing. Hygiene measures : Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the hazards and/or potential hazards that may be encountered during use. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Take off contaminated clothing and wash before reuse. Environmental exposure controls General advice 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Color Odor Lower explosion limit Upper explosion limit Flammability (solid, gas) Oxidizing properties Autoignition temperature pH Melting point/range Boiling point/boiling range : Pellets. : Translucent to white : Slight. : Note: The minimum explosive concentration (MEC) for polymer dust varies according to particle size distribution. : Note: Not applicable. : Polymer will burn but does not easily ignite. : Not considered an oxidizing agent. : > 300 °C : Note: Not applicable. : 50 - 170 °C : Note: Not applicable. 7 / 13 : See section 6. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Vapor pressure Density Water solubility Partition coefficient: n-octanol/water Viscosity, dynamic Relative vapor density Evaporation rate Explosive properties 9.2 Other information 10. Stability and reactivity 10.1 Reactivity No known reactivity hazards. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions 10.4 Conditions to avoid Conditions to avoid 10.5 Incompatible materials : Will not occur. : : : : : : : : Note: Not applicable. < 1 g/cm3 Note: Insoluble. Note: No Data Available. Note: Not applicable. Note: Not applicable. Note: Not applicable. No Data Available. Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 : Avoid contact with strong oxidizers, excessive heat, sparks or open flame. : Material may be softened by some hydrocarbons. 10.6 Hazardous decomposition products Hazardous decomposition products Thermal decomposition : Not expected to decompose under normal conditions. : Note: Carbon monoxide, olefinic and paraffinic compounds, trace amounts of organic acids, ketones, aldehydes and alcohols may be formed. Materials to avoid 8 / 13 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Chronic toxicity Carcinogenicity Germ cell mutagenicity Reproductive toxicity Effects on fertility / Effects on or via lactation Effects on Development : Not classified : Not classified Target Organ Systemic Toxicant - Single exposure : Not classified : Not an eye irritant. Mechanical irritation is possible. : Not a skin irritant. Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 : Not classified : Not classified : Not classified : Not classified : Not classified : The substance or mixture is not classified as specific target organ toxicant, single exposure. Target Organ Systemic Toxicant - Repeated exposure : The substance or mixture is not classified as specific target organ toxicant, repeated exposure. 9 / 13 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Aspiration hazard 12. Ecological information 12.1 Toxicity Ecotoxicology Assessment Acute aquatic toxicity Chronic aquatic toxicity : Not classified : Not classified : Not applicable. Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 12.2 Persistence and degradability Biodegradability 12.3 Bioaccumulative potential Bioaccumulation 12.4 Mobility in soil Additional advice : This material is not volatile and insoluble in water. Environmental fate and pathways 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB). 12.6 Other adverse effects Additional ecological information : Ecotoxicity is expected to be minimal based on the low water solubility of polymers. No data available on this product. However, birds, fish and other wildlife may eat pellets which may obstruct their intestinal tracts. : This material is not expected to bioaccumulate. : Not expected to be biodegradable. 13. Disposal considerations 13.1 Waste treatment methods Product : All recovered material should be packaged, labeled, transported and disposed of or reclaimed in conformance with 10 / 13 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 applicable laws and regulations and in conformance with good engineering practices. Reclaim where possible. Recycle if possible. 14. Transport information Not regulated for transport 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REACh status If the product has been purchased from any company of the LyondellBasell group of companies registered in the European Union, we confirm that all substances in this preparation have been pre-registered or, where required under REACh, registered, and that we have the intention to proceed with their registration in accordance with the deadlines set forth in REACh. (Regulation (EU) No. 1907/2006) Other international regulations Global Inventory Status The ingredients of this product are compliant with the following chemical inventory requirements or exemptions. *Additional Explanatory Status Statements follow the table, as necessary. Country/Region Inventory Status Description Australia AICS Compliant Canada DSL Compliant China IECSC Compliant Europe REACH See REACH Compliance Statement Japan ENCS Compliant Korea KECI Compliant New Zealand NZIoC Compliant Philippines PICCS Compliant United States of America TSCA Compliant Contact product.safety@lyondellbasell.com for additional global inventory information. 15.2 Chemical Safety Assessment No information available. 11 / 13 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 16. Other information Material safety datasheet sections which have been updated: First Edition June 30 2014 Disclaimer Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 Multiple legal entities and registration numbers may be displayed in Section 1. The Recipient shall refer to the shipping documents to identify the legal entity that supplied this product. This document is generated for the purpose of distributing health, safety, and environmental data. Information is correct to the best of our knowledge at the date of the SDS publication. It is not a specification sheet nor should any displayed data be construed as a specification. Before using a product sold by a company of the LyondellBasell family of companies, users should make their own independent determination that the product is suitable for the intended use and can be used safely and legally. SELLER MAKES NO WARRANTY; EXPRESS OR IMPLIED (INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY WARRANTY) OTHER THAN AS SEPARATELY AGREED TO BY THE PARTIES IN A CONTRACT. This product(s) may not be used in: (i) any U.S. FDA Class I, Health Canada Class I, and/or European Union Class I medical devices, without prior notification to Seller for each specific product and application; or (ii) the manufacture of any of the following, without prior written approval by Seller for each specific product and application: U.S. FDA Class II Medical Devices; Health Canada Class II or Class III Medical Devices; European Union Class II Medical Devices; film, overwrap and/or product packaging that is considered a part or component of one of the aforementioned medical devices; packaging in direct contact with a pharmaceutical active ingredient and/or dosage form that is intended for inhalation, injection, intravenous, nasal, ophthalmic (eye), digestive, or topical (skin) administration; tobacco related products and applications, electronic cigarettes and similar devices, and pressure pipe or fittings that are considered a part or component of a nuclear reactor. Additionally, the product(s) may not be used in: (i) U.S. FDA Class III Medical Devices; Health Canada Class IV Medical Devices; European Class III Medical Devices; (ii) applications involving permanent implantation into the body; (iii) life-sustaining medical applications; and (iv) lead, asbestos or MTBE related applications. All references to U.S. FDA, Health Canada, and European Union regulations include another country’s equivalent regulatory classification. The presentation of numerical data, such as that used for physical and chemical properties and toxicological values, is expressed using a comma (,) to separate digits into groups of three and a period (.) as the decimal marker. For example, 1,234.56 mg/kg = 1 234,56 mg/kg. Adflex, Adstif, Adsyl, Akoafloor, Akoalit, Alastian, Alathon, Aquathene, Avant, Catalloy, Clyrell, Dexflex, Flexathene, Hifax, Histif, Hostacom, Hostalen, Indure, Integrate, Koattro, Lucalen, Luflexen, Lupolen, Metocene, Microthene, Moplen, Nexprene, Petrothene, Plexar, Pristene, Pro-Fax, Purell, Sequel, Softell, Starflex, Ultrathene, and Valtec are trademarks owned or used by the LyondellBasell family of companies. 12 / 13 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 and No. 453/2010 Lupolen 2426K Version 1.0 Disclaimer Revision Date 07/25/2014 Gen. Variant: SDS_GB Print Date 09/19/2014 SDS No.: BE8226 13 / 13